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745 Welding, Cutting, and Brazing Safety
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Substances in Welding Smoke

When welding metals, using fluxes, or during decomposition processes, various chemical substances in the form of fumes and gases can be generated.

Welding produces a variety of hazardous chemical substances in the smoke.

Some of the common chemical substances encountered in welding fumes and related processes include:

  • Metal Oxides: During welding, metal oxides are formed due to the reaction between the metal being welded and oxygen in the air. These can include oxides of iron, aluminum, chromium, nickel, manganese, and other metals present in the base metal or filler material.
  • Ozone: Ozone (O3) can be produced by the ultraviolet radiation from the welding arc, especially during the welding of materials containing zinc or other metals with strong oxidation potential. Ozone can irritate the respiratory system.
  • Nitrogen Oxides: Welding in an environment with nitrogen or in the presence of air containing nitrogen can lead to the formation of nitrogen oxides (NOx), primarily nitrogen dioxide (NO2). Nitrogen oxides are toxic gases and can cause respiratory irritation and other health issues.
  • Carbon Monoxide: Carbon monoxide (CO) can be generated when carbon-containing materials, such as paint or coatings, are present during welding. CO is a colorless and odorless gas that is highly toxic and can lead to carbon monoxide poisoning.
  • Hazardous Metals: Welding fumes may contain hazardous metals, such as lead, cadmium, chromium, nickel, and manganese. These metals can be present in the base metal, filler materials, or coatings, and their fumes can pose serious health risks upon inhalation.
  • Volatile Organic Compounds (VOCs): Some welding processes involve the use of solvents, paints, or coatings that can release volatile organic compounds. These compounds can contribute to poor indoor air quality and may have harmful effects on human health.
  • Decomposition Products: When welding materials that contain additives, such as coatings, adhesives, or plastics, decomposition products can be released. These products can include various gases, vapors, and particles, which may have toxic or irritating properties.

It's important to note that the specific chemical substances produced during welding or related processes can vary depending on the materials being welded, the welding method, the presence of coatings or fluxes, and other factors.

To see more information on the various chemicals listed above, you can visit the OSHA's Occupational Chemical Database.

Knowledge Check Choose the best answer for the question.

6-5. What causes decomposition products to be formed while welding?